Product ID:BALL POWDER PROPELLANT,P/N 10542743-3
MSDS Date:04/10/1992
FSC:1376
NIIN:01-192-4164
MSDS Number: BPZVJ

OLIN CORPORATION

120 LONG RIDGE ROAD
STAMFORD, CT 06904-1355
US

Emergency Phone: 800-OLIN-911(800-654-6911)

Info Phone: 203-356-2000

Cage: 99530

OLIN CORPORATION

4500 NORWALK, CT 06856-4500 US

Telephone: 203-750-3000/800-511-MSDS

Cage: 99530

NITROGLYCERIN (NG) (SARA III)

CAS: 55-63-0

RTECS: QX2100000

Fraction By Weight: 0-40%

OSHA PEL S,C, 0.2 MG/M3 STEL

ACGIH TLV: S, 0.46 MG/M3; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

DIBUTYL PHTHALATE (SARA III)

CAS: 84-74-2

RTECS: TI0875000

Fraction By Weight: 0-10%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

POLYESTER ADIPATE

Fraction By Weight: 0-10%

ETHYL CENTRALITE

CAS: 85-98-3

RTECS: FE0350000

Fraction By Weight: 0-10%

OSHA PEL NOT KNOWN

ACGIH TLV: NOT KNOWN

ROSIN ACID

CAS: 8050-09-7

Fraction By Weight: 0-2%

ETHYL ACETATE (SARA III)

CAS: 141-78-6

RTECS: AH5425000

Fraction By Weight: 0-1.5%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

DIPHENYLAMINE

CAS: 122-39-4

RTECS: JJ7800000

Fraction By Weight: 0-1.5%

OSHA PEL 10 MG/M3

ACGIH TLV: 10 MG/M3

N-NITROSODIPHENYLAMINE (SARA III)

CAS: 86-30-6

RTECS: JJ9800000

Fraction By Weight: 0-1.5%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

POTASSIUM NITRATE

CAS: 7757-79-1

RTECS: TT3700000

Fraction By Weight: 0-1.5%

POTASSIUM SULFATE

CAS: 7778-80-5

RTECS: TT5900000

Fraction By Weight: 0-1.5%

TIN DIOXIDE.TIN(IV) OXIDE.

CAS: 18282-10-5

RTECS: XQ4000000

Fraction By Weight: 0-1.5%

OSHA PEL 2 MG(SN)/M3

ACGIH TLV: 2 MG(SN)/M3

2-NITRODIPHENYLAMINE

CAS: 119-75-5

Fraction By Weight: 0-1.3%

GRAPHITE,NATURAL

CAS: 7782-42-5

RTECS: MD9659600

Fraction By Weight: 0-1%

OSHA PEL 15 MPPCF RDUST

ACGIH TLV: 2 MG/M3 RDUST; 9293

CALCIUM CARBONATE.OSHA PEL 5 MG/M3 RESP FRACTION.ACGIH FOR

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: 0-1%

OSHA PEL 15 MG/M3 TOTAL DUST

ACGIH TLV: 10 MG/M3 TOTAL DUST

REMAINDER TO 100%.

CAS: 9004-70-0

RTECS: QW0970000

LD50 LC50 Mixture:NOT KNOWN
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:DIPHENYLAMINE MAY CAUSE KIDNEY
DAMAGE.THE LOW CONCENTRATION OF THIS MATERIAL IN,AND NATURE OF,THE
PRODUCT WOULD PRECLUDE DEVELOPMENT OF SUCH AN EFFECT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:IRRITATION WITH INFLAMMATION OF
CONJUNCTIVA.SKIN:IRRITATION.INGESTION:IRRITATION TO GI
TRACT.INHALATION:IRRITATION TO
NOSE,MOUTH,THROAT,LUNGS.NITROGLYCERIN MAY CAUSE DILATION OF BLOOD
VESSELS W/ DROP IN BLOOD PRESSURE,HEADACHE,CYCNOSIS,MENTAL
CONFUSION.NAUSEA,VOMITING & ABDOMINAL PAIN MAY ALSO OCCUR.
Medical Cond Aggravated by Exposure:ANEMIA AND CARDIOVASCULAR DISEASE.

First Aid:EYES:IMMED FLUSH W/ LGE AMTS OF WATER FOR AT LEAST 15 MIN.IF
IRRIT DEVELOPS,CALL MD. SKIN:IMMED FLUSH W/ WATER FOR 15 MIN.CALL
MD. INGESTION:IMMED DRINK LGE QTIES OF WATER.INDUCE VOMITING.CALL
MD.DO N OT GIVE ANYTHING BY MOUTH IF UNCON OR IF HAVING CONVL.
INHALATION:REMOVE TO FRESH AIR.IF BREATHING IS DIFFICULT,ADMIN
O*2,KEEP PATIENT WARM & AT REST.CALL MD.IF UNCON,ARTF RESP SHOULD
BE GIVEN IMMED.

Extinguishing Media:USE EXTINGUISHING MEDIA COMPATIBLE FOR SURROUNDING
PRODUCTS.IF MATERIAL ITSELF IS ON FIRE,DELUGE WITH WATER.
Fire Fighting Procedures:IN CASE OF FIRE,USE NORMAL FIRE FIGHTING
EQUIP.RESPONSE TO MATL REQUIRES USE OF SELF-CONTAINED BREATHING
APPARATUS.FIGHT FIRES FROM REMOTE LOCATION (SEE SUPP)
Unusual Fire/Explosion Hazard:CAN IGNITE DUE TO IMPACT OR STATIC
DISCHARGE.

Spill Release Procedures:PROD MAY REPRESENT EXPLO HAZ.REMOVE SOURCES OF
IGNIT.STOP SPILL & NOTIFY APPROP PERS.WET SPILL MATL PRIOR TO CLEAN
UP.USE NON-SPARKING/PLASTIC UTENSILS.WEAR FLAME RETARDANT CLOTHING
& SELF-CONTAINED B REATHING APPRATUS.WATER RELEASE:CREATE (SEE
SUPP)
Neutralizing Agent:NOT KNOWN

Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED
PLACE AWAY FROM ALL SOURCES OF IGNIT.DO NOT STORE AT TEMP
>38C,SUBJECT TO MECH SHOCK,EXPOSE TO DIRECT LIGHT.
Other Precautions:STORE IN ORIGINAL SHIPPING CONTAINERS FOR EXPLOSION
VENTING PURPOSES.CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL
CONTAMINATION FROM THE USE OF THIS MATERIAL.DO NOT TAKE
INTERNALLY.AVOID CONTACT WITH S KIN,EYES,AND CLOTHING. (SEE SUPP
DATA)

Respiratory Protection:RESPIRATORY PROTECTION NOT NORMALLY NEEDED.IF
SIGNIFICANT DUSTING OCCURS,WEAR A NIOSH/MSHA APPROVED DUST
RESPIRATOR WITH HIGH EFFICIENCY FILTERS.
Ventilation:LOCAL EXHAUST VENTILATION IS RECOMMENDED IF SIGNIFICANT
DUSTING OCCURS.OTHERWISE,USE GENERAL EXHAUST VENTILATION.
Protective Gloves:IMPERMEABLE GLOVES
Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS.
Other Protective Equipment:IMPERVIOUS BOOT,APRON,PROTECTIVE SUIT AND
HARD HAT.
Work Hygienic Practices:UPON CONTACT WITH SKIN OR EYES,WASH OFF WITH
WATER.REMOVE CONTAMINATED CLOTHING IMMED & LAUNDER BEFORE REUSE.
Supplemental Safety and Health
CONTRACT DAAA09-91-C-0494.BULK DENSITY:0.5-1 G/CC.FIRE FIGHT PROC:OR
EXPLOSIVE RESISTANT BUNKER.SPILL PROC:OVERFLOW DAM W/ FILTRATION
CAPABILITIES TO RETAIN MATL.DIVERT WATER FLOW OR STOP IF POSSIBLE.
GATHER WET MATL.KEEP MATL DAMP.OTHER PREC:SHELF LIFE INDEFINITE
WHEN KEPT UNDER 100F.

Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN
Decomp Temp:Decomp Text:>122F,>50C
Vapor Pres:<1 MMHG
Spec Gravity:1.2-1.6
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:ODORLESS,GRANULAR SOLID.
Percent Volatiles by Volume:<2

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS,BASES,AMINES,OXIDIZERS.
Stability Condition to Avoid:TEMP ABOVE 120C,IMPACT,STATIC
DISCHARGE,DIRECT SUNLIGHT,OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE,OXIDES
OF NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISP MUST BE IAW FED,STATE,& LOC REGS.COORDINATE
W/ SUPPORTING INSTALLATION/MACOM ENVIRON OFFICE PRIOR TO DISP .HAZ
WASTE NO.D003.CAN BE DISP BY CONTROLLED OPEN BURNING IN SMALL
QTIES.SPREAD MAT L IN THIN LAYERS & IGNITE FROM REMOTE LOCATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.